(E)-N′-[4-(Dimethylamino)benzylidene]-2-methoxybenzohydrazide

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(E)-4-Bromo-N-{(E)-3-[(4-bromo-2-methyl­phen­yl)imino]­butan-2-yl­idene}-2-methyl­aniline

The title compound, C(18)H(18)Br(2)N(2), is centrosymmetric with the mid-point of the central C-C bond of the butyl group located on an inversion center. The terminal benzene ring is approximately perpendicular to the central butyl plane [dihedral angle = 71.9 (8)°]. No hydrogen bonding or aromatic stacking is observed in the crystal.

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In the title compound, C12H9BrN4O, the N'-methyl-idene-pyrazine-2-carbohydrazide and 4-bromobenzene groups are oriented at a dihedral angle of 10.57 (7)°. The hydrazide N-H group is involved in intra-molecular N-H⋯N inter-action, which generates an S(5) motif. A short C-H⋯O inter-action is formed between the methyl-idene H atom and the carbonyl O atom. It connects mol-ecules into chains extendi...

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(E)-2-Meth­oxy-N′-(4-methoxy­benzyl­idene)benzohydrazide

The mol-ecule of the title compound, C(16)H(16)N(2)O(3), displays an E configuration about the C=N bond. The dihedral angle between the two benzene rings is 99.0 (2)°. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming chains running along the b axis.

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(E)-2-Fluoro-N′-(4-nitro­benzyl­idene)benzo­hydrazide

In the title hydrazone compound, C(14)H(10)FN(3)O(3), the dihedral angle between the two substituted benzene rings is 13.7 (3)°. The mol-ecule exists in a trans configuration with respect to the central methyl-idene unit. In the crystal, mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming chains along the a axis.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810023937